Synthesis and Characterization of Iron Nanowires

The iron nanowires can be fabricated via the process in which sodium borohydride reduces iron salts in external magnetic field. The iron nanowires are found to be covered by passivated layers of iron oxide which prevent the oxidation of iron nanowires. In this process, the boron will include in iron nanowires. The average length and diameter of iron nanowires is around 1.2 micrometers and 60 nanometers, respectively. According to ICP results, the contents of B and Fe are about 1.98 wt% and 87.04 wt%, respectively, in iron nanowires. A wide variety of equipment is used to investigate the morphological, microchemical, and structural characteristics of the newly synthesized iron nanowires ––– e.g., XRD, FE‐SEM, HR‐TEM, VSM and XANES. XANES analysis indicates the boron in iron nanowires exists in the form of B₂O₃. The saturation magnetization and the coercive force of iron nanowires are 157.93 emu/g and 9.74 Oe, respectively. In‐situ images of synthesized iron nanowires during reduction process in magnetic field are observed by NSRRC transmission X‐ray microscope. Thus, this study develop a novel process to produce iron nanowires with large quantitates and can control its length and diameter by various the concentration of precursors for various applications.     

A joint measurement of efficiency and effectiveness for non-storable commodities: Integrated data envelopment analysis approaches

Efficiency and effectiveness for non-storable commodities represent two distinct dimensions and a joint measurement of both is necessary to fully capture the overall performance. This paper proposes two novel integrated data envelopment analysis (IDEA) approaches, the integrated Charnes, Cooper and Rhodes (ICCR) and integrated Banker, Charnes and Cooper (IBCC) models, to jointly analyze the overall performance of non-storable commodities under constant and variable returns to scale technologies. The core logic of the proposed models is simultaneously determining the virtual multipliers associated with inputs, outputs, and consumption by additive specifications for technical efficiency and service effectiveness terms with equal weights. We show that both ICCR and IBCC models possess the essential properties of rationality, uniqueness, and benchmarking power. A case analysis also demonstrates that the proposed novel IDEA approaches have higher benchmarking power than the conventional separate DEA approaches. More generalized specifications of IDEA models with unequal weights are also elaborated.     

A hybrid approach for optimal design of signalized road network

For a signalized road network with expansions of link capacity, the maximum possible increase in travel demands is considered while total delays for travelers are minimized. Using the concept of reserve capacity of signal-controlled junctions, the problem of finding the maximum possible increase in travel demand and determining optimal link capacity expansions can be formulated as optimization programs. In this paper, we present a new solution approach for simultaneously solving the maximum increase in travel demands and minimizing total delays of travelers. A projected Quasi-Newton method is proposed to effectively solve this problem to the KKT points. Numerical computations and comparisons are made on real data signal-controlled networks where obtained results outperform traditional methods.     

Multipoint parallel excitation and CCD-based imaging system for high-throughput fluorescence detection of biochip micro-arrays

We report the development and the characterization of a multipoint parallel excitation and CCD-based imaging system for high-throughput fluorescence detection of biochip micro-arrays. A two-dimensional array of (19×19) points with uniform intensity distribution, generated by a holographic array generator, was used for parallel excitation of two-dimensional micro-arrays of fluorescence samples. A CCD-based imaging system was used for high-throughput parallel detection and quantitative analysis of the fluorescence output. Micro-array samples of cyanine (Cy5) dye dots on silicon wafers and on glass substrates with varying concentration were used to evaluate the performance of the system. Results of fluorescence intensity measurements with varying concentration of dye and with different image acquisition time are presented. We have demonstrated that this novel approach will, in general, outperform the conventional approach in the excitation efficiency, the signal-to-noise ratio, and the throughput. The limitations and the potential improvements of the present method are discussed.     

Long-term trend in CHF2Cl (HCFC-22) from high spectral resolution infrared solar absorption measurements and comparison with in situ measurements

The average tropospheric volume mixing ratio of CHF₂Cl (HCFC-22) has been retrieved from a time series of high spectral resolution ground-based infrared solar absorption spectra recorded with the McMath Fourier transform spectrometer located at the U.S. National Solar Observatory facility on Kitt Peak in southern Arizona (31.9°N, 111.6°W, 2.09 km altitude) for the time period October 1987–November 2002. The retrievals are based on fits to the well-isolated, unresolved 2ν₆ Q branch at 829.05 cm⁻¹ and the SFIT2 retrieval algorithm. The measured daily averages show a near linear rise per year in the mean tropospheric volume mixing ratio as a function of time with a best fit yielding an average increase rate of (5.66±0.15) parts per trillion (10⁻¹²) by volume per year, corresponding to (6.47±0.17)%yr⁻¹, 1 sigma, at the beginning of the time series. The tropospheric mixing ratios retrieved from the solar spectra have been compared with monthly average surface flask sampling measurements from the Climate Monitoring and Diagnostic Laboratory (CMDL) station at Niwot Ridge, Colorado (40.0°N, 105.5°W, 3013 m altitude), archived measurement from the same location, and early CMDL northern hemisphere Pacific cruise measurements. The average ratio of the retrieved tropospheric mixing ratio relative to the CMDL surface mixing ratio is 1.053 for the overlapping 1987 to 2002 time period. The retrieved mean tropospheric mixing ratio is consistent with the surface measurements within the errors estimated for the remote sensing observations.     

Exact stability regions for quartic polynomials

Given an arbitrary real quartic polynomial, we find the exact region containing the coefficients of the polynomial such that all roots have absolute values less than 1.     

Error analysis of the L2 least‐squares finite element method for incompressible inviscid rotational flows

In this article we analyze the L² least‐squares finite element approximations to the incompressible inviscid rotational flow problem, which is recast into the velocity‐vorticity‐pressure formulation. The least‐squares functional is defined in terms of the sum of the squared L² norms of the residual equations over a suitable product function space. We first derive a coercivity type a priori estimate for the first‐order system problem that will play the crucial role in the error analysis. We then show that the method exhibits an optimal rate of convergence in the H¹ norm for velocity and pressure and a suboptimal rate of convergence in the L² norm for vorticity. A numerical example in two dimensions is presented, which confirms the theoretical error estimates. © 2004 Wiley Periodicals, Inc. Numer Methods Partial Differential Eq, 2004     

An Efficient and High‐Yield One‐Pot Synthesis of Bis(oxazoline)s

An efficient and mild one‐pot synthesis of bis(oxazoline) (BOX) ligands is developed from reactions of dicarboxy dichlorides with β‐amino alcohols in the presence of 11.0 equiv. NEt₃ followed by the addition of 3.6 equiv. methanesulfonyl chloride (MsCl). Nine different BOX ligands were prepared in excellent yields of ≥ 80%. Advantages of this improved synthesis are mild reaction conditions, short total reaction time of 9 h, and high isolated yields.     

Rapid Protein Hydrolysis by Microwave Irradiation Using Heat-Resistant Teflon-Pyrex Tubes

A rapid peptide-bond hydrolysis by means of microwave irradiation is introduced for the facile preparation of protein hydrolysates used for amino acid analysis. The optimal hydrolysis condition has been determined using several enzymes with known amino acid compositions. The effects of hydrolysis time on the recovery of various labile and hydrophobic amino acids are also exemplified in the microwave heating of standard amino acids. The method has been applied to the complete amino acid analysis with a single nonvolatile solvent of methanesulfonic acid with good recovery of tryptophan and half-cystine. It provides a radical expedition of protein and peptide hydrolysis via commercial microwave ovens and specially-designed Teflon-Pyrex tubes, circumventing the tedious procedures using vacuum-sealed pyrex lubes heating at 110°C for more than 24 h. This novel type of microwave chemistry associated with rapid peptide-bond cleavage is of great potential in the automation of the complete process of amino acid analysis starting from the preparation of protein hydrolysates.